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دکتر علیرضا حریفی مود
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Ali Reza Harifi-Mood
 
                         Associate Professor of Physical Chemistry 
                       Department of Physical Chemistry
                       Faculty of Chemistry
                       Kharazmi University
                       Mofateh Ave., Tehran, Iran
                      E-mail: alireza.harifi@gmail.com & harifi@khu.ac.ir

 
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Education
- Ph.D. in Physical Chemistry, 09/2003 – 01/2008, Sharif University of Technology, Thesis title: “Solvent effect Studies on kinetics of several organic reactions in mixture of ionic liquid and molecular solvents” thesis supervisor: Prof. M. R. Gholami.
- M.S. in Physical Chemistry, 09/1997 – 09/1999, Sharif University of Technology, Thesis title: ”Florometric study of transesterification of the Procain with aliphatic alcohol by variable-temperature kinetics method,” thesis supervisor: M. R. Gholami
- B.S. in Pure Chemistry, University of Birjand
 
 Experiences

- Associate Professor of Chemistry, Kharazmi University, Tehran, Iran, 12/2016 up now
- Sabbatical Leave, University of Regensburg, Regensburg, German, 01/2015 – 09/2016 (in Prof. Richard Buchner research group)
- Assistant Professor of Chemistry, Kharazmi University, Tehran, Iran, 09/2008 – 12/2016
- Lecturer of Chemistry, Azad University of Birjand, Birjan, Iran, 01/2000 – 09/2008

 
Research Interests
- Chemical kinetics of organic reactions
- Solvent effects on chemical rate of reactions
- Ionic liquids and Deep eutectic solvents as green solvents in chemical and physical processes
- Solute-solvent interactions and solvatochromic parameters in solvents
- The solubility of gases in solvents
- CO2 capture by solvents

 
Teaching Experience

  • General Chemistry, Physical Chemistry, Physical Organic Chemistry, Chemical kinetics

Publications

  1) Harifi-Mood A. R.; Khorshahi H. “Deep eutectic solvent as an operative media on structure-reactivity relationshipsInt. J. Chem. Kinet. 2019, 51, 511-519.
  2) Aryafar M.; Abbasi M.; Reha D.; Harifi-Mood A. R.; Minofar B. “Experimental and theoretical investigation of solvatochromic properties and ion solvation structure in DESs of reline, glyceline, ethaline and their mixtures with PEG 400J. Mol. Liq. 2019, 284, 59-67.
  3) Harifi-Mood A. R.; Abbasi M. “Preferential Solvation and Solvatochromic Parameters in Mixtures of Poly (ethylene glycol)-400 with Some Molecular Organic SolventsJ. Sol. Chem. 2018, 47, 1503-1513.
  4) Ghobadi R.; Divsalar A.; Harifi-Mood A. R.; Saboury A. A.; Eslami-Moghadam M. “How a promising anti-cancer derivative of palladium consisting phen-imidazole ligand affects bovine liver catalase functionalityJ. Photoch. Photobio. A. 2018, 364, 288-296.
  5) Harifi-Mood A. R.; Sadrzadeh S. “Dimethyl sulfoxide/deep eutectic solvents mixtures as media in the reaction of 1-fluoro-2,4-dinitrobenzene with piperidine: A solvent effect studyJ. Phys. Org. Chem. 2018, 31 (4), e3787.
  6) Harifi-Mood A. R.; Khorshahi H. “Binary mixtures of dimethyl sulfoxide with methanol, ethylene glycol, and glycerol as solvent: Solvatochromism and chemical kinetics studyJ. Mol. Liq. 2018, 259, 361-368.
  7) Ghobadi R.; Divsalar A., Harifi-Mood A. R. “Spectroscopic investigation of Bovine Liver Catalase interactions with a novel phen-imidazole derivative of platinumJ. Biomol. Struc. Dynam. 2018, 36, 656-662.
  8) Harifi-Mood A. R.; Buchner R. “Density, viscosity, and conductivity of choline chloride+ ethylene glycol as a deep eutectic solvent and its binary mixtures with dimethyl sulfoxideJ. Mol. Liq. 2017, 225, 689-695.
  9) Harifi-Mood A. R.; Ghobadi R.; Divsalar A. “The effect of deep eutectic solvents on catalytic function and structure of bovine liver catalaseInt. J. Biol. Macromol. 2017, 95, 115-120.
  10) Nasseh N.; Taghavi L.; Barikbin B.; Harifi-Mood A. R. “The removal of Cr (VI) from aqueous solution by almond green hull waste material: kinetic and equilibrium studiesJ. Water Reuse Desal. 2016, 7, 449-460.
  11) Harifi-Mood A. R.; Ghobadi R.; Matić S.; Minofar B.; Řeha D. “Solvation analysis of some Solvatochromic probes in binary mixtures of reline, ethaline, and glyceline with DMSOJ. Mol. Liq. 2016, 222, 845-853.
  12) Moradi M.; Divsalar A.; Saboury A. A.; Ghalandari B.; Harifi-Mood A. R. “Inhibitory effects of deferasirox on the structure and function of bovine liver catalase: a spectroscopic and theoretical studyJ. Biomol. Struct. Dyn. 2015, 33 (10), 2255-2266.
  13) Harifi-Mood A. R.; Hadavand, F. “Adsorption of Basic Violet 16 from Aqueous Solutions by Waste Sugar Beet Pulp: Kinetic, Thermodynamic, and Equilibrium Isotherm Studies” Chem. Spec. Bioavailab. 2015, 27, 8-14.
  14) Harifi-Mood A. R.; Faramarzi, F.; Mehrabi, Y. “Investigation of Solvent Effect on The Reaction Of 1-fluoro-2,4-dinitrobenzene with Aniline in Molecular-molecular and Ionic Liquid-molecular Solvent Mixtures” Prog. Reac. Kinet. Mech. 2015, 40, 35-47.
  15) Harifi-Mood A. R.; Aryafar, M.; Minofar, B “Specific spectroscopic behavior of Reichardtchr('39')s betaine dye in binary mixtures of tetra-n-butylammonium glycinate and tetra-n-butylammonium l-alaninate with molecular solvents” J. Mol. Liq. 2014, 197, 315-321.
  16) Salari, H.; Ahmadvand, S.; Harifi-Mood A. R.; Padervand, M.; Gholami, M. R. “Molecular-Microscopic Properties and Preferential Solvation in Protic Ionic Liquid Mixtures” J. Sol. Chem. 2013, 42 (9), 1757-1769.
  17) Harifi-Mood A. R.; Mousavi-Tekmedash A. "Linear and Nonlinear Free Energy Relationships in Nucleophilic Substitution Reaction of 2-Bromo-5- Nitrothiophene with Morpholine" Int. J. Chem. Kinet. 2013, 45, 59-67.
  18) Jamali-paghaleh, J.; Harifi-Mood A. R.; Gholami, M. R. "Reaction Kinetics Investigation of 1-Fluoro-2,4-dinitrobenzene with Substituted Anilines in Ethyl acetate-methanol Mixtures Using Linear and Nonlinear Free Energy Relationships" J. Phys. Org. Chem. 2011, 24, 1095-1100. 
  19) Harifi-Mood, A. R.; Jafarinejad A. "Solvent Polarity, Hydrogen-Bonding and Solvophobicity Effects on Nucleophilic Substitution Reaction of Benzenesulfonyl Chloride with Aniline in Aqueous and Non-aqueous Solutions of Methanol" Prog. Reac. Kinet. Mech. 2011, 36, 361-370.
  20) Harifi-Mood, A. R.; Rahmati, M.; Gholami, M. R. "Solvent Polarity and Hydrogen-Bond Effects on Nucleophilic Substitution Reaction of 2-Bromo-5-Nitrothiophene with Piperidine" Int. J. Chem. Kinet. 2011, 43, 185-190.  
  21) Salari, H.; Harifi-Mood, A. R.; Gholami, M. R. "Solvatochromic probes absorbance behavior in mixtures of 2-hydroxy ethylammonium formate with methanol, ethylene glycol and glycerol" J. Sol. Chem. 2010, 39 (10), 1509-1519.
  22) Salari, H.; Kodadadi-Moghaddam, M.; Harifi-Mood, A. R.; Gholami, M. R. "Preferential Solvation and Behavior of Solvatochromic Indicators in Mixtures of an Ionic liquid with Some Molecular Solvents" J. Phys. Chem. B 2010, 114 , 9586-9593.
  23) Harifi-Mood, A. R.; Habibi-Yangjeh, A.; Gholami, M. R. “Kinetics study of a Diels-Alder reaction in mixtures of an ionic liquid with molecular solvents” J. Phys. Org. Chem. 2008, 21, 783-788.
  24) Harifi-Mood, A. R.; Habibi-Yangjeh, A.; Gholami, M. R. “Solvent Effects on Kinetics of the Reaction between 2-Chloro-3, 5-dinitropyridine and Aniline in Aqueous and Alcoholic Solutions of [bmim]BF4Int. J. Chem. Kinet. 2007, 39, 681 -687.
  25) Harifi-Mood, A. R.; Masumpour, M. S.; Gholami, M. R. “Solvent Parameters Effects on the Second-order Rate Constants of the reaction of 2- Chloro-3,5-dinitropyridine with Aniline in Aqueous Solution of Alcohols” Prog. Reac. Kinet. Mech. 2006, 31, 117 -127.
  26) Harifi-Mood, A. R.; Habibi-Yangjeh, A.; Gholami, M. R. “Solvatochromic Parameters for Binary Mixtures of 1-(1-Butyl)-3-methylimidazolium Tetrefluoroborate with Some Protic Molecular Solvents” J. Phys. Chem. B 2006, 110 , 7073-7078.
  27) Harifi Mood, A. R.; Haghighi, S.; Gholami, M. R. “Fluorometric Variable-temperature Kinetics Investigations of the Transesterification Reaction of Procaine with Aliphatic Alcohols.” J. Pharm. Pharmaceut. Sci.  2004, 7(1), 88-91.